Mnemonic

Antifungal and Antiviral Mechanisms

A memory aid for the targets of antifungal and antiviral drugs.

Expansion

Antifungals target ergosterol or the cell wall; antivirals target viral enzymes

Expansion

Antifungals

  • Azoles (fluconazole, itraconazole, voriconazole): inhibit 14-alpha demethylase, blocking ergosterol synthesis. Potent CYP inhibitors, hence many interactions
  • Polyenes (amphotericin, nystatin): bind ergosterol directly, forming pores. Amphotericin is nephrotoxic with hypokalaemia and hypomagnesaemia
  • Echinocandins (caspofungin): inhibit beta-glucan cell wall synthesis; well tolerated
  • Terbinafine: squalene epoxidase; used for dermatophytes
  • Flucytosine: pyrimidine analogue

Antivirals

  • Aciclovir: a guanosine analogue activated by viral thymidine kinase, which gives its selectivity for herpes simplex and varicella zoster
  • Ganciclovir: for cytomegalovirus; marrow suppressive
  • Oseltamivir: neuraminidase inhibitor for influenza
  • Antiretrovirals: nucleoside and non-nucleoside reverse transcriptase inhibitors, protease inhibitors, integrase inhibitors, entry inhibitors
  • Direct acting antivirals for hepatitis C: NS5A and NS5B inhibitors, now curative

The recurring theme is selective toxicity: fungi have ergosterol where humans have cholesterol, and viral enzymes have no human counterpart, which is why aciclovir is so remarkably safe.